Amirkabir Journal of Mechanical Engineering

Amirkabir Journal of Mechanical Engineering

Experimental Investigation of the Simultaneous Effect of Temperature and Aging on Mechanical Safety and Failure Behavior of Cylindrical Lithium-Ion Batteries under Dynamic Impact

Document Type : Research Article

Authors
1 Mechanical and Energy Engineering, Shahid Beheshti University
2 Faculty of Mechanical and Energy Engineering, Shahid Beheshti University
Abstract
The present research aims to experimentally evaluate the safety behavior and failure mechanism of 18650 cylindrical lithium-ion battery cells under dynamic impact loading. To this end, a pneumatic impact testing apparatus was developed in accordance with the SAE J2464 standard to assess the simultaneous effects of initial temperature (25, 0, and -25 °C), state of charge (10% and 100%), and state of health (fresh and aged over 400 cycles). Experimental results derived from high-speed imaging and thermal data analysis indicated that at ambient temperature, impact with a critical velocity of 9.23 m/s on fully charged samples led to immediate separator rupture and extensive internal short circuit. Under these conditions, the cell voltage dropped to zero within 290 ms, and explosive thermal runaway occurred with a severe temperature rise reaching 662 °C. In contrast, the most significant finding of this study reveals a substantial enhancement in the cell's mechanical resistance at sub-zero temperatures; remarkably, at -25 °C, no penetration or exothermic reaction was recorded even at high impact velocities. Further analysis suggests that the partial solidification and increased viscosity of the electrolyte at low temperatures act as an internal support with quasi-solid behavior, thereby preventing local stress concentration and separator tearing.
Keywords
Subjects

1.      M. Ehsani, Y. Gao, S. Longo, and K. Ebrahimi, Modern Electric, Hybrid Electric, and Fuel Cell Vehicles, 3rd ed., CRC Press, Boca Raton, FL, USA, 2018.
2.       M. Pepó, S. Fullér, T. Cseke, Z. Weltsch, Advances in Standardised Battery Testing for Enhanced Safety and Innovation in Electric Vehicles: A Comprehensive Review, Batteries, 11(4) (2025) 157.
3.       F. Edler, Occupational health and safety during development and usage of lithium-ion batteries, In Lithium-Ion Batteries: Basics and Applications, Springer Berlin Heidelberg, (2018) 253-262.
4.      P. Sun, R. Bisschop, H. Niu, X. Huang, A review of battery fires in electric vehicles: Data analysis and safety strategies, Fire Technology, 56 (2020) 1361-1410.
5.       M. Chen, D. Zhou, X. Chen, W. Zhang, J. Liu, R. Yuen, J. Wang, Investigation on the thermal hazards of 18650 lithium ion batteries by fire calorimeter, Journal of Thermal Analysis and Calorimetry, 122 (2015) 755-763
6.      M. Ghiji, V. Novozhilov, K. Moinuddin, P. Joseph, I. Burch, B. Suendermann, G. Gamble, A review of lithium-ion battery fire suppression, Energies, 13(19) (2020) 5117.
7.       S. Saxena, C. Hendricks, M. Pecht, Cycle life testing and modeling of graphite/LiCoO2 cells under different state of charge ranges, Journal of Power Sources, 327 (2016) 394-400
8.       W. Li, B. Song, A. Manthiram, High-voltage positive electrode materials for lithium-ion batteries, Chemical Society Reviews, 46(10) (2017) 3006-3059.
9.       Sarkar, P. Shrotriya, I.C. Nlebedim, Parametric analysis of anodic degradation mechanisms for fast charging lithium batteries with graphite anode, Computational Materials Science, 202 (2022) 110979.
10.   X. Han, L. Lu, Y. Zheng, X. Feng, Z. Li, J. Li, M. Ouyang, A review on the key issues of the lithium ion battery degradation among the whole life cycle, ETransportation, 1 (2019) 100005.
11.   G.R. Molaeimanesh, S.M. Mousavi-Khoshdel, A.B. Nemati, Experimental analysis of commercial LiFePO4 battery life span used in electric vehicle under extremely cold and hot thermal conditions, Journal of Thermal Analysis and Calorimetry, 143 (2021) 3137-3146.
12.   D. Zhou, H. Li, Z. Li, C. Zhang, Toward the performance evolution of lithium-ion battery upon impact loading, Electrochimica Acta, 432 (2022) 141192.
13.   V. Ruiz, A. Pfrang, A. Kriston, N. Omar, P. Van den Bossche, L. Boon-Brett, A review of international abuse testing standards and regulations for lithium ion batteries in electric and hybrid electric vehicles, Renewable and Sustainable Energy Reviews, 81 (2018) 1427-1452.
14.   T. Wang, H. Liu, W. Wang, W. Jiang, Y. Xu, S. Zhu, Q. Sheng, Advances in Thermal Management of Lithium-Ion Batteries: Causes of Thermal Runaway and Mitigation Strategies, Processes, 13(8) (2025) 2499.
15.   J.S. Edge, S. O’Kane, R. Prosser, Lithium ion battery degradation: What you need to know, Physical Chemistry Chemical Physics, 23(14) (2021) 8200-8221.
16.   Z. Guo, Z. Ma, J. Liu, W. Zhao, S. Wang, H. Zhao, L. Ren, Overcharging cycle aging-induced severe degradation of safety properties of lithium-ion pouch battery cells subjected to mechanical abuse, Energy, 320 (2025) 135168.